Make Alcohol Fuel
Alcohol Fuel (Bioalcohols)
See also:
Although fossil fuels have become the dominant energy resource for the modern world, alcohol has been used as a fuel throughout history. The first four aliphatic alcohols (methanol, ethanol, propanol, and butanol)
are of interest as fuels because they can be synthesized biologically,
and they have characteristics which allow them to be used in current
engines. One advantage shared by all four alcohols is octane rating. Biobutanol has the advantage that its energy density
is closer to gasoline than the other alcohols (while still retaining
over 25% higher octane rating) - however, these advantages are
outweighed by disadvantages (compared to ethanol and methanol)
concerning production, for instance. Generally speaking, the chemical
formula for alcohol fuel is CnH2n+1OH. The larger n is, the higher the energy density.
Alcohol fuels are usually of biological rather than petroleum sources. When obtained from biological sources, they are known as bioalcohols (e.g. bioethanol). It is important to note that there is no chemical
difference between biologically produced alcohols and those obtained
from other sources. However, ethanol that is derived from petroleum
should not be considered safe for consumption as this alcohol contains
about 5% methanol and may cause blindness or death. This mixture may
also not be purified by simple distillation, as it forms an azeotropic mixture.
Bioalcohols are still in developmental and research stages. Use of
optimized crops with higher yields of energy, elimination of pesticides
and fertilizers based on petroleum, and a more rigorous accounting process will help improve the feasibility of bioalcohols as fuels.
Biologically produced alcohols, most commonly ethanol, and less commonly propanol, butanol and methanol are produced by the action of microorganisms and enzymes through the fermentation of sugars or starches (easiest), or cellulose (which is more difficult). Biobutanol (also called biogasoline) is often claimed to provide a direct replacement for gasoline, because it can be used directly in a gasoline engine (in a similar way to biodiesel in diesel engines).
Butanol is formed by ABE fermentation
(acetone, butanol, ethanol) and experimental modifications of the
process show potentially high net energy gains with butanol as the only
liquid product. Butanol will produce more energy and allegedly can be
burned "straight" in existing gasoline engines (without modification to
the engine or car),[12] and is less corrosive and less water soluble than ethanol, and could be distributed via existing infrastructures. DuPont and BP are working together to help develop Butanol.
Ethanol fuel is the most common biofuel worldwide, particularly in Brazil. Alcohol fuels are produced by fermentation of sugars derived from wheat, corn, sugar beets, sugar cane, molasses and any sugar or starch that alcoholic beverages can be made from (like potato and fruit waste, etc.). The ethanol production methods used are enzyme digestion (to release sugars from stored starches, fermentation of the sugars, distillation and drying. The distillation process requires significant energy input for heat (often unsustainable natural gas fossil fuel, but cellulosic biomass such as bagasse, the waste left after sugar cane is pressed to extract its juice, can also be used more sustainably).
Ethanol can be used in petrol engines as a replacement for gasoline;
it can be mixed with gasoline to any percentage. Most existing
automobile petrol engines can run on blends of up to 15% bioethanol
with petroleum/gasoline. Gasoline with ethanol added has higher octane,
which means that your engine can typically burn hotter and more
efficiently. In high altitude (thin air) locations, some states mandate
a mix of gasoline and ethanol as a winter oxidizer to reduce atmospheric polloution emissions.
Ethanol fuel has less BTU
energy content, which means it takes more fuel (volume and mass) to go
the same distance. More-expensive premium fuels contain less, or no,
ethanol. In high-compression engines, less ethanol, slower-burning
premium fuel is required to avoid harmful pre-ignition
(knocking). Very-expensive aviation gasoline (Avgas) is 100 octane made
from 100% petroleum. The high price of zero-ethanol Avgas does not
include federal-and-state road-use taxes.
Ethanol is very corrosive to fuel systems, rubber hoses-and-gaskets, aluminum, and combustion chambers.
It is therefore illegal to use fuels containing alcohol in aircraft
(although at least one model of ethanol-powered aircraft has been
developed, the Embraer EMB 202 Ipanema).
Ethanol is incompatible with marine fiberglass fuel tanks (it makes
them leak). For higher ethanol percentage blends, and 100% ethanol
vehicles, engine modifications are required.
Corrosive
ethanol cannot be transported in petroleum pipelines, so more-expensive
over-the-road stainless-steel tank trucks increase the cost and energy
consumption required to deliver ethanol to the customer at the pump.
In the current alcohol-from-corn production model in the United States, considering the total energy consumed by farm equipment, cultivation, planting, fertilizers, pesticides, herbicides, and fungicides made from petroleum, irrigation systems, harvesting, transport of feedstock to processing plants, fermentation, distillation, drying, transport to fuel terminals and retail pumps, and lower ethanol fuel
energy content, the net energy content value added and delivered to
consumers is very small. And, the net benefit (all things considered)
does little to reduce un-sustainable imported oil and fossil fuels required to produce the ethanol.[13]
Many car manufacturers are now producing flexible-fuel vehicles
(FFV's), which can safely run on any combination of bioethanol and
petrol, up to 100% bioethanol. They dynamically sense exhaust oxygen
content, and adjust the engine's computer systems, spark, and fuel
injection accordingly. This adds initial cost and ongoing increased
vehicle maintenance.
Efficiency falls and pollution emissions increase when FFV system
maintenance is needed (regardless of the 0%-to-100% ethanol mix being
used), but not performed (as with all vehicles). FFV internal combustion engines are becoming increasingly complex, as are multiple-propulsion-system FFV hybrid vehicles, which impacts cost, maintenance, reliability, and useful lifetime longevity.
Alcohol mixes with both petroleum and with water, so ethanol fuels
are often diluted after the drying process by absorbing environmental
moisture from the atmosphere. Water in alcohol-mix fuels reduces
efficiency, makes engines harder to start, causes intermittent
operation (sputtering), and oxidizes aluminum (carburetors) and steel components (rust).
Even dry ethanol has roughly one-third lower energy content per unit
of volume compared to gasoline, so larger / heavier fuel tanks are
required to travel the same distance, or more fuel stops are required.
With large current un-sustainable, non-scalable subsidies, ethanol fuel still costs much more per unit of distance traveled than current high gasoline prices in the United States.[14]
Methanol is currently produced from natural gas, a non-renewable fossil fuel. It can also be produced from biomass as biomethanol. The methanol economy is an interesting alternative to the hydrogen economy, compared to today's hydrogen produced from natural gas, but not hydrogen production directly from water and state-of-the-art clean solar thermal energy processes.[15]
For more information see the following links:
References
^ ButylFuel,LLC Main Page
^ Andrew Bounds (September 10 2007). "OECD warns against biofuels subsidies". Financial Times. Retrieved on 2008-03-07.
^ With only 2/3 the energy of gasoline, ethanol costs more per mile. zFacts.com (27 Apr 2007). Retrieved on 2008-03-07.
^ Hydrogen Solar home
This article is licensed under the GNU Free Documentation License. It uses material from Wikipedia Encyclopedia article "Alcohol Fuel"
|